发明名称 PROCESS FOR THE PREPARATION OF ALDEHYDES
摘要 A process for prepg. aldehydes comprises (a) prior prepg. catalyst by reacting rhodium C2-18 carboxylte dissolved in (cyclo) aliphatic or aromatic hydrocarbons with CO and H at 50-100 deg.C under 0.1-1.8 MPa to prep. rhodium complex, and (b) hydroformylating by reacting olefinic unsatd. hydrocarbons with CO and H in the liq. phase at 20- 250 deg.C under 0.1-20 MPa in the presence of previous catalyst, water and triarylphosphine aq. soln..
申请公布号 KR890003783(B1) 申请公布日期 1989.10.04
申请号 KR19870003695 申请日期 1987.04.17
申请人 RUHRCHEMIE A.G. 发明人 BACH, HANSWILHELM;RAHRMANN, HELMUT;CORNILS, BOY;KONKOL, WERNER;WIEBUS, ERNST
分类号 C07B61/00;B01J31/00;B01J31/02;B01J31/20;B01J31/24;B01J37/04;C07C45/00;C07C45/50;C07C47/02;C07C47/06;C07C47/07;C07C67/00;C07F9/50 主分类号 C07B61/00
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