发明名称 |
Negative electrode active material for lithium ion secondary battery, method for producing the same, negative electrode, and battery |
摘要 |
In the case where a silicon substance having a high theoretical capacity as a negative electrode active material for a lithium ion secondary battery is used as a negative electrode active material, such a negative electrode active material is provided that has a high initial battery capacity and suffers less deterioration in performance even when many cycles of charge and discharge are repeated. A lithium ion secondary battery using the negative electrode active material is provided. Silicon and copper (II) oxide, or silicon, metallic copper and water are pulverized and simultaneously mixed in a pulverization device, thereby providing a negative electrode active material that has good cycle characteristics and a large battery capacity. |
申请公布号 |
US9634327(B2) |
申请公布日期 |
2017.04.25 |
申请号 |
US201514793975 |
申请日期 |
2015.07.08 |
申请人 |
TOHOKU UNIVERSITY;DOWA HOLDINGS CO., LTD. |
发明人 |
Shimoi Norihiro;Tohji Kazuyuki;Tanaka Yasumitsu;Zhang Qiwu;Kai Hiroyuki |
分类号 |
H01M4/00;H01M4/485;H01M4/38;C04B35/626;H01M10/0525;H01M4/36;C04B35/58;H01M4/02;H01M10/052 |
主分类号 |
H01M4/00 |
代理机构 |
Clark & Brody |
代理人 |
Clark & Brody |
主权项 |
1. A negative electrode active material for a lithium ion secondary battery, comprising silicon, copper and oxygen as major constitutional elements, the negative electrode active material for a lithium ion secondary battery, containing fine particles of silicon having an average crystallite diameter (Dx) measured by an X-ray diffractometry using a half width of the (111) plane of the silicon phase of 50 nm or less, the negative electrode active material having average elemental ratios measured by an enemy dispersive X-ray analysis in a measurement field of 200 μm×200 μm, expressed by molar ratios, Cu/(Si+Cu+O) of from 0.02 to 0.30 and O/(Si+Cu+O) of from 0.02 to 0.30. |
地址 |
Miyagi JP |