发明名称 ELECTRODE, NONAQUEOUS ELECTROLYTE BATTERY, BATTERY PACK, AUTOMOBILE, AND VEHICLE
摘要 According to one embodiment, an electrode is provided. The electrode includes an active material containing-layer. The active material containing-layer includes active material particles containing at least one selected from a niobium titanium composite oxide and a composite oxide which is expressed by the general formula LixM11-yM2yTi6-zM3zO14+δ. The active material particles include primary particles having an average particle diameter of 0.1 to 10 μm and secondary particles having an average particle diameter of 1 to 30 μm. A pore diameter distribution of the active material containing-layer which is obtained by mercury porosimetry has a first peak which has a maximum value within a range of 0.01 to 2 μm and a second peak which has a maximum value within a range of exceeding 6 μm and equal to or smaller than 20 μm. An intensity of the second peak is 1/10 to ⅕ of an intensity of the first peak.
申请公布号 US2017077494(A1) 申请公布日期 2017.03.16
申请号 US201615260628 申请日期 2016.09.09
申请人 Kabushiki Kaisha Toshiba 发明人 IWASAKI Takuya;HARADA Yasuhiro;TAKAMI Norio
分类号 H01M4/131;H01M2/10;H01M4/525;H01M2/34;H01M4/485 主分类号 H01M4/131
代理机构 代理人
主权项 1. An electrode comprising: a current collector; and an active material containing-layer that is formed on the current collector and comprises active material particles containing at least one selected from a niobium titanium composite oxide and a composite oxide expressed by a general formula of LixM11-yM2yTi6-zM3zO14+δ, wherein the active material particles comprise primary particles having an average particle diameter within a range of 0.1 μm to 10 μm and secondary particles having an average particle diameter within a range of 1 μm to 30 μm, a pore diameter distribution of the active material containing-layer obtained by mercury porosimetry has a first peak, which has a maximum value within a range of 0.01 μm to 2 μm, and a second peak which has a maximum value within a range exceeding 6 μm and equal to or smaller than 20 μm, and an intensity of the second peak is 1/10 to ⅕ an intensity of the first peak, (wherein, in the formula, M1 is at least one kind which is selected from a group consisting of Sr, Ba, Ca, and Mg, M2 is at least one kind which is selected from a group consisting of Cs, K and Na, M3 is at least one kind which is selected from a group consisting of Al, Fe, Zr, Sn, V, Nb, Ta and Mo, and x is within a range of 2≦x≦6, y is within a range of 0<y<1, z is within a range of 0<z≦6, and δ is within a range of −0.5≦δ≦0.5).
地址 Minato-ku JP