Improvements in and relating to the purification of sulphur or sulphur bearing material

摘要

The purification of crude sulphur, or of sulphur containing materials such as spent oxide, from contaminating tarry or similar organic materials is effected by washing with a saturated solution of sulphur in carbon bisulphide. Preferably, the saturated solution is obtained by treating a portion of the crude sulphur with the solvent. In the apparatus shown, a carbon bisulphide tank 5 is connected by a pipe 8 to a series of crude sulphur extractors 1-4, tarry solution passing to a still 6 by a pipe line 9 and sulphur solution by a pipe line 10 to a still 7. Valved pipes 11 connect adjacent extractors. Carbon bisulphide is first fed from the tank 5 to the extractor 1 where it dissolves sulphur and tar. So long as the tar is present in considerable quantity, the solution is led to the still 6 but when the tar content decreases, the still 6 is disconnected and the solution is fed to the top of the extractor 2 from which it passes to the still 6 till the tar content reaches the lower limit. Meanwhile, when the solution leaving the extractor 1 is free from tar, the solution is diverted from the extractor 2 to the still 7 and is resumed to the extractor 2 after the content of sulphur falls below the economical limit. When the extractor 1 is completely exhausted, it is disconnected from the extractor 2, drained, steamed, cleaned and refilled, the carbon bisulphide from the tank 5 being diverted to the extractor 2. The procedure is repeated with regard to the extractors 3, 4 and may be made cyclic by increasing the number of extractors and connecting the first and the last. During the washing step, the flow is slow but may be rapid during extraction. Specification 314,697, [Class 90, Non-metallic elements], is referred to.