Production of Ceramic Metal Oxide Membranes by Means of Reactive Electrospinning

摘要

Traditionally, the manufacturing of ceramic metal oxide membranes is often expensive and extremely labor intensive due to the often necessary post-processing steps. The present invention discloses to a novel single-step process, to produce ceramic metal oxide membranes. More specifically, this invention relates to reactive electrospinning where a sol-gel solution containing alkoxides is electrically charged and formed a Taylor cone at the tip of a needle in an environment controlled chamber, and the Taylor cone rejects a continuous stream of alkoxide nanofibers which polymerized to form a ceramic metal oxide membrane (with and without a polymer substrate present). The manufactured membranes may be used for various applications, including dye sensitized solar cells and for carbon dioxide capturing.

主权项

1. A method for manufacturing ceramic metal oxide membranes by electrospinning comprising:
applying an electric voltage to a sol-gel solution wherein the sol-gel solution comprising a solvent, at least one metal alkoxide, and at least one polymer; jetting the sol-gel solution an electrode collector in a controlled environment with a pre-determined humidity, wherein the metal alkoxide hydrolyzed into a metal oxide, the solvent vaporizes, and a condensation reaction occurs that results in the polymerization of the metal oxide.