Molecules having certain pesticidal utilities, and intermediates, compositions, and processes related thereto

摘要

This disclosure relates to the field of molecules having pesticidal utility against pests in Phyla Nematoda, Arthropoda, and/or Mollusca, processes to produce such molecules and intermediates used in such processes, compositions containing such molecules, and processes of using such molecules against such pests. These molecules may be used, for example, as nematicides, acaricides, insecticides, miticides, and/or molluscicides. This document discloses molecules having the following formula (“Formula One”).;

主权项

1. A process comprising applying a molecule of Formula One to a locus to control a pest, in a sufficient amount to control said pest, wherein said pest is Beet Armyworm (Spodoptera exigua), Cabbage Looper (Trichoplusia ni), Green Peach Aphid (Myzus persicae) or Yellow Fever Mosquito (Aedes aegypti); wherein
(A) R1, R2, R3, R4, R5, R6, R7, R9, R10, R14, R15, and R16 is each independently selected from a group consisting of H, F, Cl, Br, I, CN, NOz, OH, C1-C4 alkyl, C2-C4 alkenyl, C2-C4 alkenyloxy, C2-C4 alkynyl, C2-C4 alkynyloxy, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C3-C6 cycloalkyl, C3-C6 cycloalkoxy, C3-C6 cycloalkenyl, or C3-C5 cycloalkenyloxy,wherein each alkyl, alkenyl, alkenyloxy, alkynyl, alkynyloxy, haloalkyl, alkoxy, haloalkoxy, cycloalkyl, cycloalkoxy, cycloalkenyl, or cycloalkenyloxy, are optionally substituted with one or more substituents independently selected from a group consisting of H, F, Cl, Br, I, CN, NO2, OH, C1-C4 alkyl, C2-C4 alkenyl, C2-C4 alkenyloxy, C2-C4 alkynyl, C1-C4 alkynyloxy, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C3-C6 cycloalkyl, C3-C6 cycloalkoxy, C3-C6 cycloalkenyl, or C3-C6 cycloalkenyloxy;(B) R8 is H;(C) L is a linker that is a bond connecting nitrogen to the carbon in the ring;(D) R11 is selected from H, (C1-C4)alkyl, (C2-C4)alkenyl, (C2-C4)alkenyloxy, (C2-C4)alkynyl, (C2-C4)alkynyloxy, (C1-C4)haloalkyl, (C1-C4)alkoxy, (C1-C4)haloalkoxy, (C1-C4)alkyl (C1-C4)alkoxy, (C3-C6)cycloalkyl, (C3-C6)cycloalkoxy, (C3-C6)cycloalkenyl, (C3-C6)cycloalkenyloxy, ((C1-C4)alkyl)) (C3-C6)cycloalkyl), C(O)(C1-C4)alkyl, C(O)phenyl, ((C1-C4)alkyl)C(O)(C1-C4)alkyl, and ((C1-C4)alkyl)C(O)O((C1-C4)alkyl),wherein each alkyl, alkenyl, alkenyloxy, alkynyl, alkynyloxy, haloalkyl, alkoxy, haloalkoxy, cycloalkyl, cycloalkoxy, cycloalkenyl, cycloalkenyloxy, and phenyl, are optionally substituted with one or more substituents independently selected from H, F, Cl, Br, I, CN, NO2, OH, oxo, and OC(O)(C1-C4)alkyl;(E) X is selected from N or CR12, wherein R12 is selected from a group consisting of H, F, Cl, Br, I, CN, NO2, OH, C1-C4 alkyl, C2-C4 alkenyl, C2-C4 alkenyloxy, C2-C4 alkynyl, C2-C4 alkynyloxy, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C3-C6 cycloalkyl, C3-C6 cycloalkoxy, C3-C6 cycloalkenyl, or C3-C6 cycloalkenyloxy;(F) R13 is selected from a group consisting of H, phenyl, or substituted phenyl,wherein said substituted phenyl is substituted with one or more substituents independently selected from a group consisting of H, F, Cl, Br, I, CN, NO2, OH, C1-C4 alkyl, C2-C4 alkenyl, C2-C4 alkenyloxy, C2-C4 alkynyl, C2-C4 alkynyloxy, C1-C4 haloalkyl, C1-C4 alkoxy, C1-C4 haloalkoxy, C3-C6 cycloalkyl, C3-C6 cycloalkoxy, C3-C6 cycloalkenyl, C3-C6 cycloalkenyloxy, OC1-C4 alkylphenyl, C(O)C1-C4 alkyl, or N(C1-C4 alkyl)(C1-C4 alkyl); and(G) Q is selected from O or S.