发明名称 テトラヒドロフランの製造方法
摘要 PROBLEM TO BE SOLVED: To produce tetrahydrofuran stably at high productivity by preventing a solid material from being deposited during a cyclodehydration reaction when the tetrahydrofuran is produced through the cyclodehydration reaction of 1,4-butanediol by using an acid catalyst having a pKa value of no greater than 4.SOLUTION: The present invention is a method for producing tetrahydrofuran by means of a cyclodehydration reaction of 1,4-butanediol in the presence of an acid catalyst having a pKa value of no greater than 4 in a reaction vessel, wherein a starting material liquid containing 1,4-butanediol made available to the reaction contains 0.01-0.35 wt.% of 2-(4-hydroxybutoxy)-tetrahydrofuran and 1-1,000 wt.ppm inclusive by concentration of nitrogen atoms of at least either of an amine and amide.
申请公布号 JP5949227(B2) 申请公布日期 2016.07.06
申请号 JP20120149684 申请日期 2012.07.03
申请人 三菱化学株式会社 发明人 小西 範和;井澤 雄輔;宇都宮 賢;田中 幸太
分类号 C07D307/08 主分类号 C07D307/08
代理机构 代理人
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