发明名称 |
NOVEL RUTHENIUM COMPLEX AND METHOD FOR PREPARING METHANOL AND DIOL |
摘要 |
Provided is a method for preparing methanol and diol from cyclic carbonate, comprising: under a hydrogen atmosphere, in an organic solvent, and with the presence of a ruthenium complex (Ru(L)XYY') and an alkali, conducting a hydrogenation reduction reaction on the cyclic carbonate or polycarbonate to obtaib methanol and diol. Also provided is a ruthenium complex prepared from ruthenium and a tridentate amido diphosphine ligand. Also provided is a deuterated methanol and deuterated diol preparation method by substituting the hydrogen and ruthenium complex with deuterium. |
申请公布号 |
EP2910540(A4) |
申请公布日期 |
2016.06.22 |
申请号 |
EP20130847202 |
申请日期 |
2013.03.22 |
申请人 |
SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY, CHINESE ACADEMY OF SCIENCES |
发明人 |
DING, KUILING;HAN, ZHAOBIN |
分类号 |
C07C31/04;B01J31/24;C07C29/136;C07C31/20;C07F19/00 |
主分类号 |
C07C31/04 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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