发明名称 NOVEL RUTHENIUM COMPLEX AND METHOD FOR PREPARING METHANOL AND DIOL
摘要 Provided is a method for preparing methanol and diol from cyclic carbonate, comprising: under a hydrogen atmosphere, in an organic solvent, and with the presence of a ruthenium complex (Ru(L)XYY') and an alkali, conducting a hydrogenation reduction reaction on the cyclic carbonate or polycarbonate to obtaib methanol and diol. Also provided is a ruthenium complex prepared from ruthenium and a tridentate amido diphosphine ligand. Also provided is a deuterated methanol and deuterated diol preparation method by substituting the hydrogen and ruthenium complex with deuterium.
申请公布号 EP2910540(A4) 申请公布日期 2016.06.22
申请号 EP20130847202 申请日期 2013.03.22
申请人 SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY, CHINESE ACADEMY OF SCIENCES 发明人 DING, KUILING;HAN, ZHAOBIN
分类号 C07C31/04;B01J31/24;C07C29/136;C07C31/20;C07F19/00 主分类号 C07C31/04
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