| 发明名称 |
METHOD FOR PRODUCING 2-ISOPROPENYL-5-METHYL-4-HEXEN-1-YL 3-METHYL-2-BUTENOATE |
| 摘要 |
Provided is a method for industrially producing 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate, which is, for example, a sex pheromone substance of vine mealybug. More specifically, there is provided a method for producing 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate, comprising a step of transesterifying 2-isopropenyl-5-methyl-4-hexen-1-ol represented by Formula (1) with alkyl senecioate represented by General Formula (2) in the presence of a catalyst, while distilling off an alcohol represented by General Formula (4) formed as a by-product, to obtain 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate represented by Formula (3).; |
| 申请公布号 |
US2016152544(A1) |
申请公布日期 |
2016.06.02 |
| 申请号 |
US201514950125 |
申请日期 |
2015.11.24 |
| 申请人 |
Shin-Etsu Chemical Co., Ltd. |
发明人 |
Yamashita Miyoshi;Kinsho Takeshi |
| 分类号 |
C07C67/03;B01J31/12;B01J31/14;C07C67/54 |
主分类号 |
C07C67/03 |
| 代理机构 |
|
代理人 |
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| 主权项 |
1. A method for producing 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate, comprising a step of transesterifying 2-isopropenyl-5-methyl-4-hexen-1-ol represented by Formula (1): with alkyl senecioate represented by General Formula (2): wherein R is a saturated or unsaturated linear alkyl group having 1 to 6 carbon atoms, in the presence of a catalyst, while distilling off an alcohol represented by General Formula (4): formed as a by-product, to obtain the 2-isopropenyl-5-methyl-4-hexen-1-yl 3-methyl-2-butenoate represented by Formula (3): |
| 地址 |
Tokyo JP |
