| 主权项 |
1. A conductive covalent-organic framework (COF) comprising:
a plurality of cores, wherein each core forms at least one covalent bond to at least one linking moiety; and wherein at least one core of the plurality of cores comprises a conductive core moiety and/or wherein at least one linking moiety comprises a conductive linking moiety, wherein the at least one core is comprises Formula Ia:wherein
R1-R12, R60-R79 are independently selected from the group consisting of H, D, FG, (C1-C6)alkyl, substituted (C1-C6)alkyl, (C1-C6)alkenyl, substituted (C1-C6)alkenyl, (C1-C6)alkynyl, substituted (C1-C6)alkynyl, hetero-(C1-C6)alkyl, substituted hetero-(C1-C6)alkyl, hetero-(C1-C6)alkenyl, substituted hetero-(C1-C6)alkenyl, hetero-(C1-C6)alkynyl, substituted hetero-(C1-C6)alkynyl, (C1-C6)cycloalkyl, substituted (C1-C6)cycloalkyl, aryl, substituted aryl, heterocycle, substituted heterocycle, wherein R5 and R6 are linked together to form a substituted or unsubstituted ring selected from the group consisting of cycloalkyl, aryl and heterocycle, wherein R7 and R8 are linked together to form a substituted or unsubstituted ring selected from the group consisting of cycloalkyl, aryl and heterocycle, wherein R9 and R10 are linked together to form a substituted or unsubstituted ring selected from the group consisting of cycloalkyl, aryl and heterocycle, and wherein R11 and R12 are linked together to form a substituted or unsubstituted ring selected from the group consisting of cycloalkyl, aryl and heterocycle. |
