摘要 |
An ethylenically unsaturated polyurethane, which is an oligomer or polymer, results from the reaction of A) an alcohol component comprising : A1) at least one hydroxylated polydiene oligomer or polymer which may optionally be alkoxylated and A2) at least one hydroxyl- functional ethylenically unsaturated compound, which is a monomer or oligomer, bearing at least one ethylenic unsaturation and B) an isocyanate component comprising at least one polyisocyanate with a functionality of at least 2, wherein the molar ratio OH/NCO is greater than 1 and wherein said polyurethane bears reactive free hydroxyl groups. Such ethylenically unsaturated polyurethanes are useful as components of curable compositions such as coatings or adhesives. |