发明名称 Stabilized Thermoplastic Copolyesters
摘要 A thermoplastic copolyester composition that is able to maintain its color and mechanical strength after exposure to full weathering is provided. More specifically, a stabilizing system is employed in the composition that contains a mixture of one or more light stabilizers (e.g., hindered amines, UV absorbers, etc.), antioxidants (e.g., sterically hindered phenols, organophosphorous compounds, etc.), and secondary amines. By selectively controlling the type and concentration of the stabilizers, the present inventor has discovered that a composition may be formed that is generally resistant to color change and crazing (i.e., micro-crack formation) upon weathering. In addition to a stabilizing system, a processing stabilizer is also employed in the copolyester resin that includes a metal salt of a fatty acid having a chain length of greater than 22 carbon atoms. The present inventor has discovered that such stabilizers are particularly effective in reducing internal stresses during fiber or film formation and thereby minimizing brittleness of the resulting article. For example, a monofilament formed from the thermoplastic copolyester resin of the present invention may exhibit an elongation at break retention percentage of from about 85% to about 150% after exposure to a Xenon arc at 2000 kJ/m2 in accordance with Test Method SAE J1960.
申请公布号 US2015299426(A1) 申请公布日期 2015.10.22
申请号 US201514725029 申请日期 2015.05.29
申请人 Ticona LLC 发明人 Mulholland Bruce M.
分类号 C08K5/3475;D01F6/62;C08K5/17;C08K5/3492;C08K5/098 主分类号 C08K5/3475
代理机构 代理人
主权项 1. A stabilized polyester composition comprising: a thermoplastic copolyester comprising a copolyetherester; a light stabilizer comprising a hindered amine or a benzotriazole present in the composition in an amount from about 0.1 wt % to about 4 wt %; an antioxidant comprising a sterically hindered phenol present in the composition in an amount of from about 0.1 wt % to about 3 wt %; a secondary amine present in the composition in an amount from about 0.1 wt % to about 2 wt %; and a lubricant comprising a metal salt of a fatty acid having a chain length of from 22 to 38 carbon atoms, wherein the lubricant constitutes from about 1 wt. % to about 5 wt. % of the composition.
地址 Florence KY US