| 摘要 |
The acidyl content of filaments, fibres, yarns, fabrics, films, or like materials having a basis of an organic ester of cellulose is reduced by treatment with a hydrolyzable halide of an amphoteric metal. Examples are titanium tetrachloride stannic chloride, and tungstic chloride or silicon tetrachloride may be used. Affinity for cotton dyes may be imparted with small loss of weight, e.g. 0,5 per cent, the melting point may be raised, e.g. to 270 DEG C., and the materials char at lower temperatures than the melting point as a warning that the temperature is too high. The solubility of the materials and their reactivity towards various reagents may be greatly affected. The halide is preferably applied in solution in a liquid having a hydrolyzing action on it, e.g. water, methyl, ethyl or isopropyl alcohol or aqueous alcohol. An acid other than that formed by hydrolysis may be applied with the halide, e.g. formic, acetic or propionic acid. Suitable solutions contain 10--40 per cent titanium chloride and 5--20 per cent acetic acid, the temperature being maintained below 50 DEG C. The time of treatment may vary from /ba1/2/be--24 hours depending on the temperature, particular halide employed. The materials may be treated by impregnation by immersion followed by removal of excess solution and batching if desired under reduced pressure or in presence of a current of air. Yarns and like materials may be treated in hank form or as packages on foraminous supsupports or while travelling through treating baths. In an example cellulose acetate yarn in hank form is impregnated with an aqueous solution containing 10--40 per cent titanium tetrachloride and 5--20 per cent acetic acid by immersion for 1 to 2 minutes. The material is then centrifuged until it contains 60--100 per cent of its weight of solution and is batched at a temperature between 10 and 20 DEG C., for 12--24 hours. It is then washed and dried. The yarns may be wound on foraminous bobbins through which the solution is pumped. In another example a cellulose acetate fabric is impregnated with the solution described above, then drawn through padding rolls set to leave in the fabric solution equal to 60--100 per cent of its weight. The fabric is batched at 10--20 DEG C., until substantially dry and is then washed and dried. Preferably the materials are treated to such an extent that they attain affinity for cotton dyes while retaining affinity for cellulose ester dyes. The invention is particularly suitable for materials of high tenacity obtained by stretching threads under the action of organic agents or of water or steam as described in Specifications 438,584, 438,585, 438,655, and 438,656. The stretched threads prior to treatment may have undergone a shrinking treatment as described in Specification 389,823. Specifications 441,868 and 441,869 also are referred to. The Provisional Specification refers also to Specifications 417,220, 429,103, 430,349, 430,350, 430,351, 432,027, 432,028, and 443,726.
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