发明名称 Process for preparing Ziegler-Natta produced polyethylene blends
摘要 A process for preparing a multimodal polyethylene product with at least two different polyethylene resins can include producing a first polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The Ziegler-Natta catalyst used for the production of the first polyethylene resin has an average particle size (D50) of at most 15 μm. The HLMI of the first polyethylene resin is between 0.01 and 5 g/10 min. The process can include separately producing a second polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The MI2 of the second polyethylene resin is between 1 and 150 g/10 min. The process can include physically blending together the first and second polyethylene resins to produce a multimodal polyethylene product. The physical blending can be performed in a device for continuously melting and blending the first and second polyethylene resins.
申请公布号 US9109105(B2) 申请公布日期 2015.08.18
申请号 US201214003214 申请日期 2012.03.02
申请人 TOTAL RESEARCH & TECHNOLOGY FELUY 发明人 Dewachter Daan;Damme Eric
分类号 C08L23/06;C08L23/08 主分类号 C08L23/06
代理机构 代理人
主权项 1. A process for preparing a multimodal polyethylene product, said multimodal polyethylene product comprising at least two different polyethylene resins, the process comprising: (a) producing a first polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor, wherein the High Load Melt Index (HLMI) of said first polyethylene resin is between 0.01 and 5 g/10 min, with the HLMI being measured by the procedure of ASTM D-1238 using a temperature of 190° C. and a load of 21.6 kg; (b) separately producing a second polyethylene resin in the presence of a Ziegler-Natta catalyst in the reactor or a separate reactor, wherein the Melt Index (MI2) of said second polyethylene resin is between 1 and 150 g/10 min, with the MI2 being measured by the procedure of ASTM D-1238 using a temperature of 190° C. and a load of 2.16 kg; and (c) physically blending together said first polyethylene resin and said second polyethylene resin to produce a multimodal polyethylene product; wherein the Ziegler-Natta catalyst used for the production of said first polyethylene resin has an average particle size (D50) of at most 15 μm, with the D50 being measured by laser diffraction analysis on a Malvern type analyzer, and wherein step (c) is performed in a device for continuously melting and blending said first polyethylene resin and second polyethylene resin.
地址 Seneffe (Feluy) BE