发明名称 NON-AQUEOUS ELECTROLYTE AND POWER STORAGE DEVICE USING SAME
摘要 Provided are a nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent, the nonaqueous electrolytic solution containing from 0.001 to 5% by mass of 1,3-dioxane and further containing from 0.001 to 5% by mass of at least one selected from a specified phosphoric acid ester compound, a specified cyclic sulfonic acid ester compound, and a cyclic acid anhydride containing a side chain having allyl hydrogen; and an energy storage device using the same. This nonaqueous electrolytic solution is capable of improving electrochemical characteristics at high temperatures and further capable of not only improving a capacity retention rate after a high-temperature cycle test but also decreasing a rate of increase of an electrode thickness.
申请公布号 US2015221985(A1) 申请公布日期 2015.08.06
申请号 US201314417670 申请日期 2013.07.29
申请人 UBE INDUSTRIES, LTD. 发明人 Abe Koji
分类号 H01M10/0569;H01M10/0525 主分类号 H01M10/0569
代理机构 代理人
主权项 1. A nonaqueous electrolytic solution, comprising an electrolyte salt dissolved in a nonaqueous solvent comprising: from 0.001 to 5% by mass of 1,3-dioxane; and from 0.001 to 5% by mass of at least one selected from the group consisting of a phosphoric acid ester compound represented by the following general formula (I), a cyclic sulfonic acid ester compound represented by the following general formula (II), and a cyclic acid anhydride comprising a side chain comprising an allyl hydrogen: wherein: each of R1 and R2 independently represents an alkyl group having from 1 to 6 carbon atoms or a halogenated alkyl group having from 1 to 6 carbon atoms, in which at least one hydrogen atom is substituted with a halogen atom; R3 represents an alkyl group having from 1 to 6 carbon atoms, an alkenyl group having from 2 to 6 carbon atoms, or an alkynyl group having from 3 to 6 carbon atoms; and each of R4 and R5 independently represents a hydrogen atom, a halogen atom, or an alkyl group having from 1 to 4 carbon atoms; wherein: each of R6 and R7 independently represents a hydrogen atom, an alkyl group having from 1 to 6 carbon atoms, in which at least one hydrogen atom is optionally substituted with a halogen atom, or a halogen atom; X represents —CH(OR8)— or —C(═O)—; and R8 represents a formyl group, an alkyl carbonyl group having from 2 to 7 carbon atoms, an alkenyl carbonyl group having from 3 to 7 carbon atoms, an alkynyl carbonyl group having from 3 to 7 carbon atoms, or an aryl carbonyl group having from 7 to 13 carbon atoms, in which at least one hydrogen atom in R8 is optionally substituted with a halogen atom.
地址 Ube-shi, Yamaguchi JP