发明名称 CONTINUOUS PRODUCTION METHOD FOR CONJUGATED DIENE POLYMER HAVING NARROW MOLECULAR WEIGHT DISTRIBUTION, AND PRODUCT PRODUCED THEREBY
摘要 <p>PROBLEM TO BE SOLVED: To provide an economical continuous polymerization method for conjugated diene copolymer that has a high cis-1,4-linkage content and a narrow molecular weight distribution.SOLUTION: There is provided a continuous production method for conjugated diene polymer in which a catalyst composition prepared by combining (a) lanthanide compound, (b) alkylating agent and (c) halogen-containing compound, and a conjugated diene monomer are contacted in hydrocarbon solvent within a continuous reaction tank, and the method comprises a step in which a non-ideal flow pattern is maintained within the continuous reaction tank, such that 10% of the reactant that entered the reaction tank at reference time tis still present within the continuous reaction tank at time t+xt[here, tis a residence time corresponding to an ideal flow within the continuous reaction tank, and x is a number larger than 1.5].</p>
申请公布号 JP2015129291(A) 申请公布日期 2015.07.16
申请号 JP20150013042 申请日期 2015.01.27
申请人 BRIDGESTONE CORP 发明人 OZAWA YOICHI;ROGGEMAN DAVID;MILLER H JERROLD;MAZAKI KOJI;LUO STEVEN;ANTKOWIAK THOMAS
分类号 C08F2/00;C08F36/06;C08F4/52;C08F4/54;C08F4/60;C08F36/00;C08F136/06 主分类号 C08F2/00
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