发明名称 Catalyst component for polymerization of olefin and preparation method
摘要 The present invention relates to a catalyst component for olefin polymerization, which comprises the reaction product of at least one organo-magnesium compound, at least one titanium-containing compound, at least one hydroxyl group-containing compound, at least one chlorine-containing organo-aluminum, boron, phosphorus or silicon compound, and at least one polybutadiene block copolymer. The catalyst component of the present invention has well-shaped particles, and a narrow particle size distribution; a polymerization reaction of olefins with the catalyst component produces well-shaped polymer particles with a high bulk density (BD) and an excellent comprehensive catalytic performance. The present invention also relates to a preparation method for said catalyst component and the application thereof, particularly in the homopolymerization and copolymerization of olefins such as ethylene, propylene, butene, hexene and octene.
申请公布号 US9068025(B2) 申请公布日期 2015.06.30
申请号 US201113817610 申请日期 2011.08.19
申请人 China Petroleum & Chemical Corporation;Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation 发明人 Wang Shibo;Liu Dongbing;Zhou Junling;Lü Xinping;Zhang Lei;Mao Bingquan;Xing Baoquan;Zhou Xin;Zhang Changli
分类号 C08F4/649;C08F10/00 主分类号 C08F4/649
代理机构 Finnegan, Henderson, Farabow, Garrett & Dunner, LLP 代理人 Finnegan, Henderson, Farabow, Garrett & Dunner, LLP
主权项 1. A catalyst component for olefin polymerization, comprising the reaction product of at least one organo-magnesium compound, at least one titanium-containing compound, at least one hydroxyl group-containing compound, at least one chlorine-containing organic compound, and at least one polybutadiene block copolymer, wherein said organo-magnesium compound is as shown in Formula (I) MgR1nCl2-n, wherein R1 is a C2-C20 hydrocarbyl group, and can be saturated or unsaturated straight chain, branched chain, or cyclo-chain, and 0<n≦2; wherein said titanium-containing compound is as shown in Formula (II) Ti(OR2)mCl4-m, wherein R2 is C2-C20 hydrocarbyl group, and can be a saturated or unsaturated straight chain, branched chain, or cyclo-chain, and 0≦m≦4; and wherein said hydroxyl group-containing compound is as shown in Formula (III) HOR3, wherein R3 is a C2-C20 hydrocarbyl group, and can be a saturated or unsaturated straight chain, branched chain, or cyclo-chain.
地址 Beijing CN