发明名称 |
Catalyst component for polymerization of olefin and preparation method |
摘要 |
The present invention relates to a catalyst component for olefin polymerization, which comprises the reaction product of at least one organo-magnesium compound, at least one titanium-containing compound, at least one hydroxyl group-containing compound, at least one chlorine-containing organo-aluminum, boron, phosphorus or silicon compound, and at least one polybutadiene block copolymer. The catalyst component of the present invention has well-shaped particles, and a narrow particle size distribution; a polymerization reaction of olefins with the catalyst component produces well-shaped polymer particles with a high bulk density (BD) and an excellent comprehensive catalytic performance. The present invention also relates to a preparation method for said catalyst component and the application thereof, particularly in the homopolymerization and copolymerization of olefins such as ethylene, propylene, butene, hexene and octene. |
申请公布号 |
US9068025(B2) |
申请公布日期 |
2015.06.30 |
申请号 |
US201113817610 |
申请日期 |
2011.08.19 |
申请人 |
China Petroleum & Chemical Corporation;Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation |
发明人 |
Wang Shibo;Liu Dongbing;Zhou Junling;Lü Xinping;Zhang Lei;Mao Bingquan;Xing Baoquan;Zhou Xin;Zhang Changli |
分类号 |
C08F4/649;C08F10/00 |
主分类号 |
C08F4/649 |
代理机构 |
Finnegan, Henderson, Farabow, Garrett & Dunner, LLP |
代理人 |
Finnegan, Henderson, Farabow, Garrett & Dunner, LLP |
主权项 |
1. A catalyst component for olefin polymerization, comprising the reaction product of at least one organo-magnesium compound, at least one titanium-containing compound, at least one hydroxyl group-containing compound, at least one chlorine-containing organic compound, and at least one polybutadiene block copolymer,
wherein said organo-magnesium compound is as shown in Formula (I) MgR1nCl2-n, wherein R1 is a C2-C20 hydrocarbyl group, and can be saturated or unsaturated straight chain, branched chain, or cyclo-chain, and 0<n≦2; wherein said titanium-containing compound is as shown in Formula (II) Ti(OR2)mCl4-m, wherein R2 is C2-C20 hydrocarbyl group, and can be a saturated or unsaturated straight chain, branched chain, or cyclo-chain, and 0≦m≦4; and wherein said hydroxyl group-containing compound is as shown in Formula (III) HOR3, wherein R3 is a C2-C20 hydrocarbyl group, and can be a saturated or unsaturated straight chain, branched chain, or cyclo-chain. |
地址 |
Beijing CN |