发明名称 METHOD FOR PRODUCING DERIVATIVE OF &bgr;-HYDROXY CARBOXYLIC ACID
摘要 PROBLEM TO BE SOLVED: To provide methods for producing an α,&bgr;-unsaturated type carboxylate and an α,&bgr;-unsaturated type carboxylate ester.SOLUTION: Provided is a method for producing an α,&bgr;-unsaturated type carboxylate including: preparing an aqueous solution containing a &bgr;-hydroxycarboxylate; and (b) heating the solution, thus dewatering the salt to form an α,&bgr;-unsaturated type carboxylate. Also provided is a method for producing an α,&bgr;-unsaturated type carboxylate ester including: reacting the α,&bgr;-unsaturated type carboxylate with alcohol to form an α,&bgr;-unsaturated type carboxylate ester. In the method for producing an α,&bgr;-unsaturated type carboxylate, the salt is selected from alkali metal salts, alkaline-earth metal salts, ammonium salts, alkyl ammonium salts and their combination, and particularly, a sodium salt or a calcium salt is used.
申请公布号 JP2015083568(A) 申请公布日期 2015.04.30
申请号 JP20140230836 申请日期 2014.11.13
申请人 CARGILL INC 发明人 TSOBANAKIS PARASKEVAS;MENG XIANGSHENG;ABRAHAM TIMOTHY W
分类号 C07C51/347;B01J21/10;B01J23/02;B01J23/04;B01J23/86;B01J27/053;B01J27/055;B01J27/16;B01J27/18;B01J27/182;B01J27/232;B01J31/10;C07B61/00;C07C51/377;C07C57/04;C07C67/08;C07C67/31;C07C67/327;C07C69/54;C07C69/66;C07C69/675;C12P7/40;C12P7/42;C12P7/52;C12P7/62 主分类号 C07C51/347
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