Organic-inorganic complexes containing a luminescent rare earth-metal nanocluster and an antenna ligand, luminescent articles, and methods of making luminescent compositions

摘要

Luminescent compositions are described comprising lanthanide-containing nanoclusters comprising lanthanide atoms bonded to at least one semimetal or transition metal via an oxygen or sulfur atom. Novel compositions include an antenna ligand complexed with the nanoclusters. The rare earth-metal nanoclusters are in the size range of 1 to 100 nm. Articles, such as solar cells, are described in which the nanoclusters (with or without antenna ligands) are dispersed in a polymer matrix. Novel methods of making luminescent films are also described.

主权项

1. A composition comprising: a polymer matrix, rare earth-metal nanoclusters dispersed in the polymer, and antenna ligands disposed on the exterior of the rare earth-metal nanoclusters; wherein the rare earth-metal nanoclusters are in the size range of 1 to 100 nm and comprise lanthanide atoms bonded to at least one semimetal or transition metal via an oxygen or sulfur atom.