发明名称 |
Method of producing macrocyclic polymers |
摘要 |
A method for producing a macrocyclic polymer comprising: (a) polymerizing a monomer using a dibrominated initiator having either an aromatic or ester moiety via atom transfer radical polymerization (ATRP) to form a polymer precursor having brominated, phenylated end groups; and (b) cyclizing the polymer precursor using intramolecular atom transfer radical coupling (ATRC) to form the macrocyclic polymer. |
申请公布号 |
US9012597(B2) |
申请公布日期 |
2015.04.21 |
申请号 |
US201113696142 |
申请日期 |
2011.05.05 |
申请人 |
Bucknell University |
发明人 |
Tillman Eric S.;Voter Andrew F. |
分类号 |
C08F293/00;C08F8/00;C08F8/48 |
主分类号 |
C08F293/00 |
代理机构 |
Saul Ewing LLP |
代理人 |
Saul Ewing LLP ;Driscoll Stephen J. |
主权项 |
1. A method for producing a macrocyclic polymer comprising:
(a) polymerizing a monomer using a dibrominated initiator having either an aromatic or ester moiety via atom transfer radical polymerization (ATRP) to form a polymer precursor having brominated, phenylated end groups; and (b) cyclizing said polymer precursor using intramolecular atom transfer radical coupling (ATRC) by activating said brominated, phenylated end groups to form said macrocyclic polymer. |
地址 |
Lewisburg PA US |