发明名称 Method of producing macrocyclic polymers
摘要 A method for producing a macrocyclic polymer comprising: (a) polymerizing a monomer using a dibrominated initiator having either an aromatic or ester moiety via atom transfer radical polymerization (ATRP) to form a polymer precursor having brominated, phenylated end groups; and (b) cyclizing the polymer precursor using intramolecular atom transfer radical coupling (ATRC) to form the macrocyclic polymer.
申请公布号 US9012597(B2) 申请公布日期 2015.04.21
申请号 US201113696142 申请日期 2011.05.05
申请人 Bucknell University 发明人 Tillman Eric S.;Voter Andrew F.
分类号 C08F293/00;C08F8/00;C08F8/48 主分类号 C08F293/00
代理机构 Saul Ewing LLP 代理人 Saul Ewing LLP ;Driscoll Stephen J.
主权项 1. A method for producing a macrocyclic polymer comprising: (a) polymerizing a monomer using a dibrominated initiator having either an aromatic or ester moiety via atom transfer radical polymerization (ATRP) to form a polymer precursor having brominated, phenylated end groups; and (b) cyclizing said polymer precursor using intramolecular atom transfer radical coupling (ATRC) by activating said brominated, phenylated end groups to form said macrocyclic polymer.
地址 Lewisburg PA US