发明名称 |
METHOD FOR PRODUCING POLYCYCLIC AROMATIC COMPOUND SUBSTITUTED BY ARYL GROUP |
摘要 |
<p>PAH is subjected to C-H/C-B coupling using a specific boron compound, a palladium compound, and o-chloranil to produce a compound in which a C-H bond of the PAH is directly arylated regioselectively in a simple manner. When the substrate and the boron compound are appropriately selected, a larger PAH can also be obtained by further performing an annulation reaction after the coupling reaction. Similarly, when PAH is subjected to C-H/C-H cross-coupling using a specific aromatic compound, a palladium compound, and o-chloranil, a compound in which a C-H bond of the PAH is directly arylated regioselectively can be produced in a simple manner. When the substrate and the aromatic compound are appropriately selected in this case, a larger PAH can also be obtained by further performing an annulation reaction after the cross-coupling reaction.</p> |
申请公布号 |
EP2730554(A4) |
申请公布日期 |
2015.04.15 |
申请号 |
EP20120797336 |
申请日期 |
2012.06.08 |
申请人 |
NATIONAL UNIVERSITY CORPORATION NAGOYA UNIVERSITY |
发明人 |
ITAMI, KENICHIRO;MOCHIDA, KENJI;KAWASUMI, KATSUAKI;SEGAWA, YASUTOMO;KAJINO, TOMONORI |
分类号 |
C07C2/86;C07B61/00;C07C5/44;C07C15/20;C07C15/30;C07C15/38;C07C17/263;C07C22/08;C07C25/22 |
主分类号 |
C07C2/86 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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