| 摘要 |
A photovoltaic dye cell including a cell housing having an at least partially transparent cell wall; an electrolyte, disposed within the housing, and containing a charge transfer species; an at least partially transparent electrically conductive layer disposed on a first interior surface of the cell wall, within the photovoltaic cell; an anode disposed on the electrically conductive layer, the anode including: (i) a sintered porous film containing sintered titania, the film disposed on a broad face of the electrically conductive layer, and adapted to make intimate contact with the electrolyte, and (ii) a dye, absorbed on a surface of the porous film, the dye and the porous film adapted to convert photons to electrons, by means of the charge transfer species; and a cathode disposed substantially opposite the anode, and including a catalytic surface disposed to contact the electrolyte; wherein the film has an overall average pore size (d50) falling within a range of 25 to 45 nanometers, contains less than 700 ppm carbon, and has an at least bi-modal pore size distribution in which a first mode has an average pore size of at most 23 micrometers, and in which a second mode has an average pore size of at least 25 micrometers. |
