发明名称 Peroxide cured TPV
摘要 Thermoplastic elastomer compositions and methods for making same. The elastomer composition can include at least one partially cured rubber component that is an ethylene-alpha-olefin-vinyl norbornene elastomeric polymer, and at least one thermoplastic component. The rubber component is at least partially cured using a peroxide curative in an amount effective to yield a cure level of the rubber component of at least 85%. The rubber component has a molecular weight distribution (MWD) less than 6, and a branching index greater than 0.60.
申请公布号 US8969481(B2) 申请公布日期 2015.03.03
申请号 US200913127826 申请日期 2009.11.05
申请人 ExxonMobil Chemical Patent Inc. 发明人 Ellul Maria D.;Ravishankar Periagaram S.
分类号 C08L23/04;C08L45/00;C08L23/10;C08L23/16 主分类号 C08L23/04
代理机构 代理人
主权项 1. A thermoplastic elastomer,comprising: about 60 wt % to about 90 wt % of at least partially cured metallocene-produced ethylene-propylene-vinyl norbornene elastomeric rubber component, wherein the vinyl norbornene content of the rubber component is 0.2 wt % to 1.5 wt % and the ethylene content is 50 wt % to 80 wt %; and about 10 wt % to about 40 wt % of at least one thermoplastic component; wherein the rubber component is at least partially cured using a peroxide curative to yield a cure level of the rubber component of at least 95%, wherein the rubber component has a molecular weight distribution (MWD) of less than 4, a weight average molecular weight (Mw) of from 50,000 to 150,000 g/mole, a branching index greater than 0.70, and a Mooney viscosity, ML(1+4 at 125° C.), as determined according to ASTM D1646, of 10 to 26.2; andwherein the thermoplastic elastomer has (as determined according to ASTM D412):an ultimate tensile stength of 3.6-5.1 MPa, an elongation at break of 124% to 222%, and a tension set of 10.0% to 23.0%.
地址 Houston TX US