发明名称 Use of quaternary ammonium compounds as collectors in froth flotation processes
摘要 The present invention relates to the use of a polymeric quaternary ester product as a collector in a froth flotation process, to a method for froth flotation utilizing the polymeric quaternary ester, to the polymeric quaternary ester as such, and to methods for the production of the polymeric quaternary ester.
申请公布号 US8936159(B2) 申请公布日期 2015.01.20
申请号 US201113697801 申请日期 2011.05.25
申请人 Akzo Nobel Chemicals International B.V. 发明人 Gorochovceva Natalija;Klingberg Anders
分类号 B03D1/016;B03D1/01;C08G63/685;B03D1/02 主分类号 B03D1/016
代理机构 代理人 Kellam Matthew D.
主权项 1. A method for froth flotation of a mineral-containing ore, the method comprising contacting the ore with: a) a product obtainable by the condensation, in one or several steps, of: i) a compound having the formulawhere R1 is a hydrocarbyl group having 7-24 carbon atoms, which may be branched or linear, saturated or unsaturated, AO is an alkyleneoxy group having 2-4 carbon atoms, n is a number between 0 and 20, and Y is O, C(═O)NH or NZ, where Z is a group R2, where R2 is a C1-C4 alkyl group, or the benzyl group, provided that when Y is NZ or C(═O)NH, then n is ≧1; ii) a dicarboxylic acid or a derivative thereof having the formula (IIa) or (IIb)where D is —OH, —Cl, or —OR4, where R4 is a C1-C4 alkyl group; R3 is an alkylene radical of formula —(CH2)z—, in which z is an integer from 0 to 10, and in which the alkylene radical may be substituted by 1 or 2 —OH groups; the group —CH═CH—, a cycloalkylene, a cycloalkenylene, or an arylene group; and iii) an alkanolamine having the formula (III)where each x independently is a number between 1 and 5 and Σx on average is a number between 2 and 10, AO is an alkyleneoxy group having 2-4 carbon atoms, R5 is a C1-C3 alkyl group or a group [AO]x where AO and x have the same meaning as above;followed by reaction with an alkylating agent R6X, where R6 is a hydrocarbyl group and X− is an anion derived from the alkylating agent R6X; or b) a product obtainable by the condensation of: i) compound (I), or of a compound obtained by partial or total quaternisation of (I);ii) (IIa) or (IIb); andiii) a compound obtained by partial or total quaternisation of the alkanolamine (III).
地址 Amersfoort NL
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