发明名称 |
METHODS AND SYSTEMS FOR ACIDIZING SUBTERRANEAN FORMATIONS WITH TREATMENT FLUIDS CONTAINING DUAL-FUNCTIONING CHELATING AGENTS |
摘要 |
<p>When used outside the pH range at which metal ion complexation normally occurs, aminopolycarboxylic acids can moderate the reaction rate of acids with carbonate minerals. Methods for treating a subterranean formation can comprise: providing a treatment fluid comprising an aqueous carrier fluid, an acid, and a chelating agent comprising an aminopolycarboxylic acid, the treatment fluid having a pH below that at which the carboxylic acid groups of the chelating agent are substantially protonated and the chelating agent is ineffective for complexing a metal ion; introducing the treatment fluid into a subterranean formation comprising a carbonate mineral; reacting the acid with the carbonate mineral, such that the acid at least partially spends and the pH of the treatment fluid rises; and once the pH of the treatment fluid rises above a pKa value for one or more of the carboxylic acid groups, complexing a metal ion with the chelating agent.</p> |
申请公布号 |
WO2014209649(A1) |
申请公布日期 |
2014.12.31 |
申请号 |
WO2014US42479 |
申请日期 |
2014.06.16 |
申请人 |
HALLIBURTON ENERGY SERVICES, INC. |
发明人 |
REYES, ENRIQUE ANTONIO;SMITH, ALYSSA LYNN;BEUTERBAUGH, AARON M. |
分类号 |
C09K8/72;C09K8/035;E21B43/22 |
主分类号 |
C09K8/72 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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