发明名称 |
NOVEL IRON-BASED CATALYSTS AND TREATMENT PROCESS THEREFOR FOR USE IN FISCHER-TROPSCH REACTIONS |
摘要 |
A Fischer-Tropsch catalyst, useful for conversion of synthesis gas to olefins, is prepared from a catalyst precursor composition including iron oxide and an alkali metal on a substantially inert support, and then treated by a process including as ordered steps (1) reduction in a hydrogen-containing atmosphere at a pressure of 0.1 to 1 M Pa and a temperature from 280 °C to 450 °C; (2) carburization in a carbon monoxide-containing atmosphere at a pressure from 0.1 to 1 M Pa and a temperature from 200 °C to less than 340 °C; and (3) conditioning in a hydrogen- and carbon monoxide-containing atmosphere at a pressure from 0.1 to 2 MPa and a temperature from 280 °C to 340 °C. The resulting catalyst exhibits at least one improvement selected from (1) increased overall activity; (2) reduced break-in time; (3) slowed rate of deactivation; and (4) increased time to onset of deactivation; when compared to an otherwise identical catalyst precursor composition treated by one or some, but not all, of the given steps and/or under different conditions. |
申请公布号 |
WO2014210089(A1) |
申请公布日期 |
2014.12.31 |
申请号 |
WO2014US43983 |
申请日期 |
2014.06.25 |
申请人 |
DOW GLOBAL TECHNOLOGIES LLC |
发明人 |
DAVIDIAN, THOMAS;RUITENBEEK, MATTHIJS;KOEKEN, ADRIANUS;VOS, MARJOLEIN;WIELEMAKER, MARCO F. |
分类号 |
B01J23/78;B01J35/02;C07C1/04;C10G2/00 |
主分类号 |
B01J23/78 |
代理机构 |
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