发明名称 RECYCLE OF REACTOR EFFLUENT IN AN ALKYLAROMATIC PROCESS
摘要 A method of making alkylaromatics is described. The process includes recycling a portion of the alkylation reaction zone effluent back to the alkylation zone to maintain the product quality while reducing energy usage.
申请公布号 US2014378724(A1) 申请公布日期 2014.12.25
申请号 US201313923125 申请日期 2013.06.20
申请人 UOP LLC 发明人 Majumder Debarshi
分类号 C07C2/66 主分类号 C07C2/66
代理机构 代理人
主权项 1. A process for preparing linear alkylaromatics by the alkylation of an aromatic compound with olefins having between about 8 and 20 carbon atoms comprising: contacting the aromatic compound and a feed comprising a mixture of about 12 to about 30 wt % olefins and about 70 to about 88 wt % other components in an alkylation zone under alkylation conditions including a catalytically effective amount of a catalyst to provide an alkylation product containing monoalkylaromatics, dialkylaromatics, unreacted aromatic compound, and unreacted other components; dividing the alkylation product into a first portion and a second portion; recycling the first portion of the alkylation product to the alkylation zone; separating the second portion of the alkylation product into an aromatic-rich fraction containing the unreacted aromatic compound and a substantially aromatic compound-free fraction containing alkylaromatics, unreacted other components, and dialkylaromatics; separating the substantially aromatic-free fraction into an other component-rich fraction containing the unreacted other components and a substantially other component-free fraction containing the monoalkylaromatics, and dialkylaromatics; and separating the substantially other component-free fraction into a monoalkylaromatic fraction containing the linear monoalkylaromatics and a heavies fraction containing the dialkylaromatics.
地址 DES PLAINES IL US