| 摘要 |
Provided is a ruthenium complex that is represented by general formula (1*) and is useful as an asymmetric reduction catalyst.;(In the formula, * is an asymmetric carbon atom; R1 is an arenesulfonyl group, and the like; R2 and R3 are a phenyl group, and the like; R10 through R14 are selected from a hydrogen atom, C1-10 alkyl group, and the like, but R10 through R14 are not simultaneously hydrogen atoms; X is a halogen atom and the like; j and k are each either 0 or 1; and j+k is 0 or 2.); |
| 主权项 |
1. A ruthenium complex represented by the following general formula (1*): wherein each * represents an asymmetric carbon atom, R1 represents an alkyl group having 1 to 10 carbon atoms; an alkanesulfonyl group having 1 to 10 carbon atoms and optionally substituted with a halogen atom; an arenesulfonyl group optionally substituted with an alkyl group having 1 to 10 carbon atoms, a halogenated alkyl group having 1 to 10 carbon atoms, or a halogen atom; an alkoxycarbonyl group having 2 to 11 carbon atoms in total; or a benzoyl group optionally substituted with an alkyl group having 1 to 10 carbon atoms, R2 and R3 each independently represent an alkyl group having 1 to 10 carbon atoms; a phenyl group optionally substituted with an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or a halogen atom; or a cycloalkyl group having 3 to 8 carbon atoms, or R2 and R3 may together form a ring, R10, R12, and R14 each independently represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or a trisubstituted alkylsilyl group, R11 and R13 each independently represent a hydrogen atom, an alkyl group having 2 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or a trisubstituted alkylsilyl group, provided that the case where all of R10 to R14 simultaneously represent hydrogen atoms is excluded, X represents a trifluoromethanesulfonyloxy group, a p-toluenesulfonyloxy group, a methanesulfonyloxy group, a benzenesulfonyloxy group, a hydrogen atom, or a halogen atom, j and k each represent 0 or 1, and j+k is 0 or 2. |
