发明名称 リチウムイオン二次電池負極用黒鉛材料およびその製造方法、リチウムイオン二次電池
摘要 A graphite material for a negative electrode of a lithium ion secondary cell is capable of suppressing capacity degradation caused by the repetition of charging and discharging cycles, storage in a charged state, floating charging and the like. A graphite material for a negative electrode of a lithium ion secondary cell, in which Lc (112), which is a crystallite size in a c-axis direction calculated from a (112) diffraction line measured using powder X-ray diffraction method, is within 4.0 nm to 30 nm, a carbon-derived spectrum appearing in electron spin resonance spectroscopy, which is measured using an X band, is in a range of 3200 gauss (G) to 3400 gauss (G), a relative signal intensity ratio (I4.8K/I40K) of the signal intensity (I4.8K) of the spectrum measured at a temperature of 4.8 K to the signal intensity (I40K) of the spectrum measured at a temperature of 40 K is within 1.5 to 3.0, and DeltaHpp, which is a line width of the spectrum calculated from a primary derivative spectrum of the temperature of 4.8 K, is within 20 gauss (G) to 40 gauss (G).
申请公布号 JP5623262(B2) 申请公布日期 2014.11.12
申请号 JP20100277230 申请日期 2010.12.13
申请人 JX日鉱日石エネルギー株式会社 发明人 石丸 紀代;鈴木 貴志;河野 岳史
分类号 H01M4/587 主分类号 H01M4/587
代理机构 代理人
主权项
地址