发明名称 クロスカップリング反応用触媒、及びこれを用いた芳香族化合物の製造方法
摘要 <p>The present invention provides a process for efficiently producing an alkylated aromatic compound in good yield, by a cross-coupling reaction between an alkyl halide and an aromatic magnesium reagent. A process for producing an aromatic compound represented by Formula (1): R-Ar'(1) wherein R is a hydrocarbon group, and Ar' is an aryl group; the process comprising: reacting a compound represented by Formula (2): R-X(2) wherein X is a halogen atom, and R is as defined above, with a magnesium reagent represented by Formula (3): Ar'-MgY(3) wherein Y is a halogen atom, and Ar' is as defined above, in the presence of a catalyst for cross-coupling reactions comprising an iron compound and a bisphosphine compound represented by Formula (4): wherein Q is a divalent group derived from an aromatic ring by removing two hydrogen (H) atoms on adjacent carbon atoms; and each Ar is independently an aryl group.</p>
申请公布号 JP5622573(B2) 申请公布日期 2014.11.12
申请号 JP20100518946 申请日期 2009.03.10
申请人 发明人
分类号 C07F9/50;B01J31/24;C07C1/32;C07C13/18;C07C13/28;C07C13/615;C07C15/107;C07C17/32;C07C25/18;C07C29/32;C07C33/20;C07C41/30;C07C43/21;C07C67/343;C07C69/612 主分类号 C07F9/50
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