发明名称 Method of coloring surface of zirconium-based metallic glass component
摘要 A method of coloring a surface of a zirconium-based metallic glass component that includes the step of imparting interference colors by carrying out an anodizing process using an alkaline solution to form a film having a thickness of 300 nm or less on the surface of the zirconium-based metallic glass component.
申请公布号 US8865253(B2) 申请公布日期 2014.10.21
申请号 US201113009082 申请日期 2011.01.19
申请人 NGK Insulators, Ltd.;Tohoku University 发明人 Muramatsu Naokuni;Suzuki Ken;Inoue Akihisa;Kimura Hisamichi
分类号 C25D11/26 主分类号 C25D11/26
代理机构 Burr & Brown, PLLC 代理人 Burr & Brown, PLLC
主权项 1. A method of coloring a surface of a zirconium-based metallic glass component, comprising the step of; imparting an interference color selected from gray, blue, purple, gold, yellow, brown and black by forming a film having a thickness of 80 nm or more and 300 nm or less on the surface of the zirconium-based metallic glass component, by heating the zirconium-based metallic glass component at a temperature of 400° C. or more and 450° C. or less for a time period of 1 to 15 minutes, the temperature being equal to or lower than a crystallization temperature of zirconium-based metallic glass in an inert gas atmosphere having an oxygen concentration of 80 ppm or more and 500 ppm or less, wherein the gray color is formed by heating in an argon gas atmosphere having an oxygen concentration of about 300 ppm and a flow rate of about 1 L/min, the blue color is formed by heating in an argon gas atmosphere having an oxygen concentration of about 300 ppm and a flow rate of about 2 L/min, the purple color is formed by heating in an argon gas atmosphere having an oxygen concentration of about 480 ppm and a flow rate of about 1 L/min, the gold color is formed by heating in an argon as atmosphere having an oxygen concentration of about 100 ppm and a flow rate of about 2 L/min, the yellow color is formed by heating in an argon gas atmosphere having an oxygen concentration of about 80 ppm and a flow rate of about 2 L/min, the brown color is formed by heating in a nitrogen gas atmosphere having an oxygen concentration of about 150 ppm and a flow rate of about 1 L/min, and the black color is formed by heating in a nitrogen gas atmosphere having an oxygen concentration of about 100 ppm and a flow rate of about 1 L/min.
地址 Nagoya JP
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