发明名称 |
The method for preparing titanium containing SAPO-34 molecular sieve and the method of preparation for light olefin using titanium containing SAPO-34 molecular sieve therefrom |
摘要 |
The present invention relates to a preparing method of a SAPO-34 molecular sieve containing titanium, a SAPO-34 molecular sieve containing titanium prepared by the method and a preparation method of light olefin from methanol using the SAPO-34 molecular sieve. More specifically, the method of the present invention, wherein a titanium precursor is firstly added and then the phosphoric acid is added unlike an existing method which means a synthetic gel is formed after the titanium precursor is added, and the SAPO-34 molecular sieve manufactured by the method has the same structure of porous chabazite mineral and forms Ti well in a molecular sieve whose catalyst activity is relatively large. In a case of using the SAPO-34 molecular sieve as a catalyst for an MTO reaction which manufactures light olefin from oxygenate compounds like methanol, the SAPO-34 molecular sieve is allowed to improve catalyst activity and catalyst life compared with a Ti-SAPO-34 molecular sieve manufactured by the SAPO-34 and an existing method and to increase yield and selection degree of light olefin. |
申请公布号 |
KR101451296(B1) |
申请公布日期 |
2014.10.16 |
申请号 |
KR20130043758 |
申请日期 |
2013.04.19 |
申请人 |
KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY |
发明人 |
KIM, TAE WAN;JEONG, SOON YONG;CHAE, HO JEONG;KIM, CHUL UNG;JEONG, KWANG EUN;KIM, JOO WAN |
分类号 |
C01B39/04;C07C5/22;C07C9/02 |
主分类号 |
C01B39/04 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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