发明名称 |
AMINO ACID PREPARATION METHOD COMPRISING A STEP OF HYDROFORMYLATION OF AN UNSATURATED FATTY NITRILE |
摘要 |
A method for synthesizing a ω-amino acid compound having formula HOOC—R′—CH2NH2, where R is an alkyl radical including between 6 and 15 carbon atoms or an alkylene radical including between 6 and 15 carbon atoms and between 0 and 2 unsaturations. The method including the following steps: 1) hydroformylation of an unsaturated fatty nitrile selected from compounds having formula R1—CH═CH—[(CH2)q—CH═CH]m—(CH2)r—CN, said step consisting in reacting the nitrile with the carbon monoxide and dihydrogen such as to obtain at least one fatty nitrile aldehyde having formula HOC—R′—CN; 2) dioxygen oxidation, wherein the nitrile aldehyde obtained in step 1) is converted into fatty nitrile acid having formula HOOC—R′—CN; and 3) reduction, in which the nitrile acid obtained in step 2) is converted into co-amino acid having formula HOOC—R′—CH2NH2. |
申请公布号 |
EP2785682(A1) |
申请公布日期 |
2014.10.08 |
申请号 |
EP20120810327 |
申请日期 |
2012.12.03 |
申请人 |
ARKEMA FRANCE;CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE;UNIVERSITÉ DE RENNES 1 |
发明人 |
DUBOIS, JEAN-LUC;COUTURIER, JEAN-LUC;CARPENTIER, JEAN-FRANÇOIS;TERNEL, JÉRÉMY |
分类号 |
C07C227/04;C07C229/08;C07C253/30;C07C255/19 |
主分类号 |
C07C227/04 |
代理机构 |
|
代理人 |
|
主权项 |
|
地址 |
|