发明名称 CURING COMPOSITIONS FOR FLUOROPOLYMERS
摘要 Diaminospirobisindane diols, curable compositions, curative compositions, cured articles, and methods of curing are described.
申请公布号 US2014288232(A1) 申请公布日期 2014.09.25
申请号 US201214355901 申请日期 2012.11.07
申请人 3M INNOVATIVE PROPERTIES COMPANY 发明人 Grootaert Werner M.A.;Wendland Michael S.;Griesgraber George W.
分类号 C08F14/26;C08K3/04 主分类号 C08F14/26
代理机构 代理人
主权项 1. A curable composition comprising a fluoroelastomer comprising a nitrogen-containing cure site monomer and a curative selected from the group consisting of curatives of Formula I and II, where Formula I is: wherein each R1 is independently selected from H, Cl, Br, I, a C1 to C20 linear, cyclic, or branched alkyl group, a C5 to C20 aryl group, a C5 to C20 alkaryl group, a C5 to C20 aralkyl group, and NH2; each R2 is —OH; each R3 is independently selected from H, Cl, Br, I, a C1 to C20 linear, cyclic, or branched alkyl group, a C5 to C20 aryl group, a C5 to C20 alkaryl group, a C5 to C20 aralkyl group, and NH2; each R4 is independently selected from H, Cl, Br, I, a C1 to C20 linear, cyclic, or branched alkyl group, and a C5 to C20 aryl group, a C5 to C20 alkaryl group, a C5 to C20 aralkyl group; each R5 and R6 is independently selected from an —H, a C1 to C20 linear or branched alkyl group, a C3 to C40 alkyl group that forms a spiro group when both R5 and R6 are part of the same cyclic structure, a C5 to C40 aryl group, a C5 to C40 alkaryl group, a C5 to C40 aralkyl group that optionally forms a spiro group when both R5 and R6 are part of the same cyclic structure, an —OH, and together with one another a C═O; provided that at least one of R1 and R3 on each ring is an —NH2; and Formula II is: wherein each R1 is independently selected from H, Cl, Br, I, a C1 to C20 linear, cyclic, or branched alkyl group, a C5 to C20 aryl group, a C5 to C20 alkaryl group, a C5 to C20 aralkyl group, and NH2; each R2 is —OH; each R3 is independently selected from H, Cl, Br, I, a C1 to C20 linear, cyclic or branched alkyl group, a C5 to C20 aryl group, a C5 to C20 alkaryl group, a C5 to C20 aralkyl group, and NH2; each R4 is independently selected from H, Cl, Br, I, a C1 to C20 linear, cyclic or branched alkyl group, a C5 to C20 aryl group, a C5 to C20 alkaryl group, and a C5 to C20 aralkyl group; each R5 is independently selected from an —H, a C1 to C20 linear, cyclic, or branched alkyl group, a C5 to C40 aryl group, a C5 to C40 alkaryl group, and a C5 to C40 aralkyl group; provided that at least one of R1 and R3 on each ring is an —NH2.
地址 St. Paul MN US