发明名称 Process for preparing dienyl-ruthenium complexes
摘要 The present invention relates to a single-stage process for preparing dienyl-ruthenium complexes of the formula Ru(+II)(dienyl)2, wherein an Ru(II) starting compound of the formula Ru(X)p(Y)q is reacted with a diene ligand in the presence of an inorganic and/or organic base in a single-stage process. Here, polar organic solvents, preferably mixtures of polar organic solvents with water, are used. The dienyl-ruthenium complexes prepared according to the invention are used as precursors for homogeneous catalysts, for producing functional coatings and for therapeutic applications.
申请公布号 US8829220(B2) 申请公布日期 2014.09.09
申请号 US200912995537 申请日期 2009.05.30
申请人 Umicore AG & Co., KG 发明人 Doppiu Angelino;Rivas-Nass Andreas;Karch Ralf;Winde Roland
分类号 C07F15/00;C07F17/02 主分类号 C07F15/00
代理机构 Smith, Gambrell & Russell LLP 代理人 Smith, Gambrell & Russell LLP
主权项 1. Process for preparing dienyl-ruthenium complexes of the formula Ru(+II)(dienyl)2 wherein a ruthenium starting compound of the formula Ru(+II)(X)p(Y)q where X=an anionic group, Y=an uncharged two-electron donor ligand, p=an integer from 1 to 2, q=an integer from 1 to 6, is reacted with a diene ligand L in the presence of an inorganic and/or organic base in a single-stage process.
地址 Hanau-Wolfgang DE