发明名称 |
Process for preparing dienyl-ruthenium complexes |
摘要 |
The present invention relates to a single-stage process for preparing dienyl-ruthenium complexes of the formula Ru(+II)(dienyl)2, wherein an Ru(II) starting compound of the formula Ru(X)p(Y)q is reacted with a diene ligand in the presence of an inorganic and/or organic base in a single-stage process. Here, polar organic solvents, preferably mixtures of polar organic solvents with water, are used. The dienyl-ruthenium complexes prepared according to the invention are used as precursors for homogeneous catalysts, for producing functional coatings and for therapeutic applications. |
申请公布号 |
US8829220(B2) |
申请公布日期 |
2014.09.09 |
申请号 |
US200912995537 |
申请日期 |
2009.05.30 |
申请人 |
Umicore AG & Co., KG |
发明人 |
Doppiu Angelino;Rivas-Nass Andreas;Karch Ralf;Winde Roland |
分类号 |
C07F15/00;C07F17/02 |
主分类号 |
C07F15/00 |
代理机构 |
Smith, Gambrell & Russell LLP |
代理人 |
Smith, Gambrell & Russell LLP |
主权项 |
1. Process for preparing dienyl-ruthenium complexes of the formula
Ru(+II)(dienyl)2 wherein a ruthenium starting compound of the formula
Ru(+II)(X)p(Y)q where
X=an anionic group, Y=an uncharged two-electron donor ligand, p=an integer from 1 to 2, q=an integer from 1 to 6, is reacted with a diene ligand L in the presence of an inorganic and/or organic base in a single-stage process. |
地址 |
Hanau-Wolfgang DE |