发明名称 ZWITTERIONIC AZO DYESTUFFS FOR COLOURING KERATIN-INCLUDING FIBRES
摘要 The invention relates to agents for coloring keratinic fibers, in particular human hair, including in a cosmetic carrier at least one compound of the formula (I). The structures the of the general formula (I) have a heterocycle A which bears a quaternary nitrogen atom and thus a positive charge. The invention furthermore relates to the use of these novel azo dyes in agents for coloring hair and to the dyes themselves.
申请公布号 US2014237735(A1) 申请公布日期 2014.08.28
申请号 US201414270175 申请日期 2014.05.05
申请人 Henkel AG & Co. KGaA 发明人 Gross Wibke;Nemitz Ralph;Moch Melanie
分类号 A61K8/49;C07D277/42;C07D235/30;C07D233/88;C07D249/14;C07D213/76;C07D285/135;C07D285/08;C07D261/14;C07D277/82;C07D263/58;A61Q5/10;C07D231/38 主分类号 A61K8/49
代理机构 代理人
主权项 1. An agent for coloring keratinic fibers included in a cosmetic carrier, the agent comprising: at least one compound of the formula (I), in which: R1 and R2 mutually independently denote hydrogen, a C1-C6 alkyl group, a C2-C6 alkenyl group, a hydroxyl group, a C1-C6 alkoxy group, halogen, an amino group, an acetylamino group, a nitro group, or a nitrile group, oralternatively, R1 and R2 form a 5- or 6-membered, saturated or unsaturated, carbocyclic or heterocyclic ring if R1 and R2 are in ortho position relative to one another;X denotes O or N—R3;R3 denotes hydrogen, a C1-C6 alkyl group, a C2-C6 alkenyl group, a C2-C6 hydroxyalkyl group, a C2-C6 polyhydroxyalkyl group, a C1-C6 cyanoalkyl group, an aryl-C1-C6-alkyl group, or a group —Y′—O—SO2—OM;Y and Y′, in each case, mutually independently denote (CH2)n, C2H4—(OC2H4)n, (CH2)n—O—(CH2)m, or (CH2)n—N(R8)-(CH2)m, in which n and m in each case mutually independently denote an integer from 1 to 6,A denotes one of structures (II) to (XIII), in which: R4 and R5, in each case, mutually independently denote hydrogen, a C1-C6 alkyl group, a C2-C6 alkenyl group, a hydroxyl group, a C1-C6 alkoxy group, halogen, an amino group, an acetylamino group, a C1-C6 alkylsulfonyl group, or a nitrile group, orR4 and R5 form a 5- or 6-membered, saturated or unsaturated, carbocyclic or heterocyclic ring if R4 and R5 are in ortho position relative to one another;R6 and R7 mutually independently denote a C1-C6 alkyl group, a C2-C6 alkenyl group, or a C2-C6 hydroxyalkyl group;R8 denotes hydrogen, a C1-C6 alkyl group, a C2-C6 alkenyl group, or a C2-C6 hydroxyalkyl group; andM denotes hydrogen, an alkali metal or half an equivalent of an alkaline earth metal.
地址 Dusseldorf DE