发明名称 Bi- or tricyclic sterically hindered alkoxyamines and process for their preparation
摘要 The instant invention pertains to novel bi- or tricyclic sterically hindered alkoxyamines, their precursors, a process for their preparation and their use as light stabilizers for polymers or coatings, as flame retardants, as peroxide substitutes (rheology modifiers) or carbon radical scavengers.
申请公布号 US8809533(B2) 申请公布日期 2014.08.19
申请号 US201314045860 申请日期 2013.10.04
申请人 BASF SE 发明人 Hauck Stefan;Fischer Walter;Schoening Kai-Uwe
分类号 C07D491/04;C08K5/353;C08K5/3435;C07D209/52;C07D211/94 主分类号 C07D491/04
代理机构 代理人 Stevenson Tyler A.
主权项 1. A compound of formula (Ib) wherein G1, G2, G3 and G4 are independently alkyl of 1 to 4 carbon atoms or G1 and G2 and/or G3 and G4 are together tetramethylene or pentamethylene; E is independently straight or branched chain C1-C24alkyl, straight or branched chain C2-C18alkenyl, C3-C20alkinyl, C3-C12cycloalkyl, C5-C12cycloalkenyl, phenyl, naphthyl or C7-C15phenylalkyl; where said straight or branched chain C1-C24alkyl, straight or branched chain C2-C24alkenyl, C3-C12cycloalkyl, C5-C12cycloalkenyl or C3-C20alkinyl can be substituted by one or more -halogen, —OH, —OR122, —NH2, —NHR122, —N(R122)2, —NHCOR122, —NR122COR122, —OCOR122, —COR122, —SO2R122, —SR122, —SOR122, —P(OR122)3, —P(O)(OR122)2 or P(R122)3; where said straight or branched chain unsubstituted or substituted C1-C24alkyl, straight or branched chain unsubstituted or substituted C2-C24alkenyl, C5-C12cycloalkyl, C5-C12cycloalkenyl or C2-C18alkinyl can also be interrupted by one or more —O—, —NH— or —NR122— groups or combinations thereof; and where said phenyl, naphthyl or C7-C15phenylalkyl can also be substituted by one or more halogen, —CN, —CF3, —NO2,  —NHR122, —N(R122)2, —OH, —OR122 or —COR122; wherein R122 is hydrogen, straight or branched chain C1-C18alkyl, straight or branched chain C2-C18 alkenyl, C3-C10cycloalkyl, phenyl, naphthyl or C7-C15phenylalkyl; and W is CH2 or CH3; if W is CH3, k is 0; and if W is CH2, Y is a direct bond, CH2 or C(CH3)2.
地址 Ludwigshafen DE