Organic electroluminescent device with host materials having same or similar IP, EA and T1 values

摘要

Disclosed is a highly reliable organic electroluminescent device, in particular, a phosphorescent organic electroluminescent device using a low-molecular-weight host material, wherein a good balance between electron and hole injection and an efficient mechanism of phosphorescence are maintained. The organic electroluminescent device contains a light-emitting layer between an anode layer and a cathode layer and the light-emitting layer comprises a phosphorescent dopant material and a host material with a molecular weight of not more than 10,000. The host material is composed of a first host material and a second host material that is different from the first host material and the first host material differs from the second host material by not more than 0.1 eV in the ionization potential (IP), by not more than 0.1 eV in the electron affinity (EA), and by not more than 0.1 eV in the triplet energy (T1).

主权项

1. An organic electroluminescent device containing a light-emitting layer formed by a wet film-forming process between an anode and a cathode wherein the light-emitting layer comprises a phosphorescent dopant material and a host material having a molecular weight of not more than 10,000, the said host material is composed of a first host material and a second host material that is different from the first host material, the first host material or the second host material is a heterocyclic compound represented by the following formula (1), the ratio by weight of the first host material to the second host material is 90:10 to 10:90, and the first host material differs from the second host material by less than 0.1 eV in the ionization potential (IP), by less than 0.1 eV in the electron affinity (EA), and by less than 0.1 eV in the triplet energy (T1); wherein in formula (1): ring A is an aromatic ring represented by formula (1a) and is fused to the adjacent rings at arbitrary positions and ring B is a heterocycle represented by formula (1b) and is fused to the adjacent rings at arbitrary positions; R in formulas (1) and (1a) is independently hydrogen or a monovalent substituent and the adjacent substituents optionally together form a ring; L1 in formula (1b) is independently an aromatic hydrocarbon group or an aromatic heterocyclic group; L is an n-valent aromatic hydrocarbon group or an n-valent aromatic heterocyclic group; n is 1-4; and when n is 2 or more, the fused heterocycle containing rings A and B are identical with or different from one another.