发明名称 |
Preparation of Conjugated Aromatic/Heteroaromatic Oligomer-Containing Dielectric Polymers and Their Applications |
摘要 |
A π-conjugated aromatic/heteroaromatic oligomer-containing vinyl monomer is generally provided, which can include a polymerizable group, a linker group, and a π-conjugated aromatic/heteroaromatic side chain. The π-conjugated aromatic/heteroaromatic side chain includes a first cyclopentadiene ring covalently attached to the linder group, a set of second cyclopentadiene rings covalently attached to the first cyclopentadiene ring, and a third cyclopentadiene ring positioned at a terminal end of the π-conjugated aromatic/heteroaromatic side chain such that the set of second cyclopentadiene rings is positioned between the first cyclopentadiene ring and the third cyclopentadiene ring. Methods are also provided for forming a polymer via polymerizing the π-conjugated aromatic/heteroaromatic oligomer-containing vinyl monomer, and for grafting a π-conjugated aromatic/heteroaromatic oligomer-containing polymer onto a surface of a nanomaterial. |
申请公布号 |
US2014206821(A1) |
申请公布日期 |
2014.07.24 |
申请号 |
US201414160879 |
申请日期 |
2014.01.22 |
申请人 |
Tang Chuanbing;Qiao Yali;Ploehn Harry J.;Islam MD. Sayful |
发明人 |
Tang Chuanbing;Qiao Yali;Ploehn Harry J.;Islam MD. Sayful |
分类号 |
C08F28/06 |
主分类号 |
C08F28/06 |
代理机构 |
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代理人 |
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主权项 |
1. A π-conjugated aromatic/heteroaromatic oligomer-containing vinyl monomer comprising a polymerizable group, a linker group, and a π-conjugated aromatic/heteroaromatic side chain, and wherein the polymerizable group comprises a vinyl group, and further wherein the π-conjugated aromatic/heteroaromatic side chain comprises:
a first cyclopentadiene ring covalently attached to the linder group and having substituted or unsubstituted first hetero-atom substituted therein; a set of second cyclopentadiene rings covalently attached to the first cyclopentadiene ring, wherein the set comprises a number (n) of repeating second cyclopentadiene rings covalently bonded together in a chain, with n being an integer of 1 to about 25, and wherein each of the second cyclopentadiene rings has a substituted or unsubstituted second hetero-atom substituted therein; and a third cyclopentadiene ring positioned at a terminal end of the π-conjugated aromatic/heteroaromatic side chain such that the set of second cyclopentadiene rings is positioned between the first cyclopentadiene ring and the third cyclopentadiene ring, wherein the third cyclopentadiene ring has a substituted or unsubstituted third hetero-atom substituted therein. |
地址 |
Columbia SC US |