发明名称 Use of a co-feed in the coupling of toluene with a carbon source
摘要 A process for making styrene is disclosed that includes providing toluene, a co-feed, and a C1 source to a reactor containing a catalyst, reacting toluene with the C1 source in the presence of the catalyst and the co-feed to form a product stream containing ethylbenzene and styrene. The co-feed can be selected from the group of water, carbon monoxide, hydrogen, and combinations thereof.
申请公布号 US8785705(B2) 申请公布日期 2014.07.22
申请号 US201213457500 申请日期 2012.04.27
申请人 Fina Technology, Inc. 发明人 Chinta Sivadinarayana;Thorman Joseph L.;Butler James R.
分类号 C07C15/46;C07C15/073 主分类号 C07C15/46
代理机构 代理人
主权项 1. A process for making styrene comprising: providing toluene, a co-feed, and a C1 source to a reactor comprising a catalyst comprising X zeolite and at least one promoter selected from the group consisting of Ce, Cu, P, Cs, B, Co, Ga, and combinations thereof, wherein the C1 source is selected from the group consisting of methanol, formaldehyde formalin, trioxane, methylformcel, paraformaldehyde, methylal, dimethyl ether, and combinations thereof; and reacting toluene with the C1 source in the presence of the catalyst and the co-feed to form a product stream comprising ethylbenzene and styrene; wherein the co-feed is selected from the group consisting of carbon monoxide, hydrogen, and combinations thereof.
地址 Houston TX US