发明名称 PROCESS FOR THE SYNTHESIS OF OMEGA-UNSATURATED NITRILE-ACID/ESTER IN WHICH TWO TYPES OF CROSS METATHESIS ARE ALTERNATED CONSECUTIVELY, SWING PROCESS
摘要 The invention relates to a process for the synthesis of a monounsaturated nitrile-ester (acid) by cross metathesis starting from an unsaturated compound comprising at least one trivalent nitrile, acid or ester functional group, characterized in that it comprises a stage in which two types of cross metathesis are alternated consecutively: - a first type of cross metathesis cm1 with an acrylic compound II chosen from acrylonitrile, acrylic acid or an acrylic ester, one of the compounds I or II comprising a nitrile functional group and the other of these compounds II or I comprising an acid or ester functional group, and - a second type of cross metathesis cm2 with a light C2 to C4 alkene compound III, preferably with ethylene. The invention also relates to a process for the synthesis of an α,ω-amino ester (acid) obtained by a process comprising a stage in which the two types of cross metathesis defined above are alternated consecutively, followed by a hydrogenation stage.
申请公布号 WO2014106766(A1) 申请公布日期 2014.07.10
申请号 WO2013IB00017 申请日期 2013.01.07
申请人 ARKEMA FRANCE 发明人 DUBOIS, JEAN-LUC;COUTURIER, JEAN-LUC
分类号 C07C253/30;C07C6/04;C07C57/02;C07C69/593;C07C255/30;C07F15/00 主分类号 C07C253/30
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