发明名称 Polyamide membranes with fluoroalcohol functionality
摘要 A polymeric membrane includes an active layer on a support. The active layer includes a polymer with a backbone, and the backbone has attached thereto at least one fluoroalcohol moiety.
申请公布号 US8754139(B2) 申请公布日期 2014.06.17
申请号 US200912390127 申请日期 2009.02.20
申请人 International Business Machines Corporation;Central Glass Co., Ltd. 发明人 Allen Robert David;Young-Hye Na;Sooriyakumaran Ratnam;Fujiwara Masaki;Yamanaka Kazuhiro
分类号 C08J5/20 主分类号 C08J5/20
代理机构 Shumaker & Sieffert, P.A. 代理人 Shumaker & Sieffert, P.A.
主权项 1. A polymeric membrane comprising an active layer that is on a support, wherein the active layer comprises a polymer with a backbone having attached thereto at least one fluoroalcohol moiety, wherein the polymer in the active layer is derived by reacting a chemical mixture (A) and a chemical mixture (B), wherein (A) and (B) are immiscible with each other, and wherein: (A) is an aqueous base comprising a monomeric polyamine reactant having one or more hexafluoroalcohol groups represented by Formula 1: wherein R0 represents an organic group selected from the group consisting of aliphatic, alicyclic, aromatic, heterocyclic groups and combinations thereof, m is an integer of 2 or more, and n is an integer of 1 or more, and (B) is organic, and comprises a monomeric polyfunctional acyl halide reactant represented by Formula 2: R1COX)p  Formula 2wherein R1 represents an organic group selected from the group containing aliphatic alicyclic, aromatic, heterocyclic groups and combinations thereof, X is selected from the group consisting of fluorine, chlorine, bromine and iodine, and p represents an integer of 2 or more.
地址 Armonk NY US