发明名称 EPOXIDE AND THIOEPOXIDE FUNCTIONAL, POLYMERIZABLE COMPOSITIONS AND METHODS OF PREPARING OPTICAL ARTICLES THEREFROM
摘要 Provided is a thioepoxide functional polymerizable composition comprising a reaction product of thiourea and an epoxide functional, polymerizable composition. The epoxide functional, polymerizable composition comprises a reaction product prepared from a reaction mixture comprising: (a) a monomer comprising at least one ethylenically unsaturated ester functional monomer having an epoxide functional group; and(b) a compound having two or more thiol groups.;The reactants (a) and (b) are reacted via a Michael addition reaction in the presence of a base to form an epoxide functional reaction product. Also provided are methods of preparing an optical article using the polymerizable compositions.
申请公布号 US2014155572(A1) 申请公布日期 2014.06.05
申请号 US201313961443 申请日期 2013.08.07
申请人 PPG INDUSTRIES OHIO, INC. 发明人 Bojkova Nina V.
分类号 G02B1/04 主分类号 G02B1/04
代理机构 代理人
主权项 1. A thioepoxide functional, polymerizable composition comprising a reaction product of: (a) thiourea; and (b) an epoxide functional, polymerizable composition comprising a reaction product prepared from a reaction mixture comprising: (i) a monomer comprising at least one ethylenically unsaturated ester functional monomer having an epoxide functional group; and (ii) a compound having two or more thiol groups; wherein the reactants (i) and (ii) are reacted via a Michael addition reaction in the presence of a base to form an epoxide functional reaction product.
地址 Cleveland OH US