High T_gepoxy systems for composite applications

摘要

A thermoset resin, including the reaction product of: an epoxy resin mixture including at least one cycloaliphatic epoxy resins; a cycloaliphatic anhydride hardener; and a catalyst; wherein the reaction product has a glass transition temperature greater than or equal to 210° C. Also disclosed is a process for forming a thermoset resin, including: admixing two or more epoxy resins and a cycloaliphatic anhydride hardener to form a curable composition, wherein the epoxy resins include at least one cycloaliphatic epoxy resin; thermally curing the curable composition at a temperature of at least 150° C. to result in a thermoset resin having a glass transition temperature of at least 210° C. Such curable compositions may include: 35 to 65 weight percent of an epoxy resin mixture having at least one cycloaliphatic epoxy resins; 35 to 65 weight percent of a cycloaliphatic anhydride hardener; and from greater than 0 to 10 weight percent of a catalyst.

主权项

1. A curable composition comprising an epoxy resin mixture, wherein the epoxy resin mixture comprises 70 weight percent to 100 weight percent of cycloaliphatic epoxy resin based on a total weight of the epoxy resin mixture; a cycloaliphatic anhydride hardener; greater than 10 to 30 weight percent of a toughening agent based on a total weight of the curable composition; and a catalyst; wherein the curable composition when cured forms a reaction product, the resulting reaction product having (i) a glass transition temperature greater than or equal to about 210° C. as measured by differential scanning calorimetry or dynamic mechanical thermal analysis; (ii) a tensile modulus of at least about 260000 psi; (iii) an elongation at break of at least about 5 percent; and (iv) a peak stress of at least about 7000 psi.