发明名称 |
Nanoporous Silica Polyamine Composites with Surface-bound Zirconium (IV) and Methods of Use |
摘要 |
Silica polyamine composites (SPC) made from silanized amorphous nano-porous silica gel and poly(allylamine) (BP-1) were functionalized with phosphorus acid using the Mannich reaction, resulting in a phosphonic acid modified composite (BPAP). Zirconium (IV) was immobilized on BPAP. Arsenate anions strongly adsorbed on the ZrBPAP composite in the pH range 2 to 8, while arsenite only adsorbed well at pH 10. Regeneration of the resin was carried out successfully for As(V) and As(III) using 2M-H2SO4. Four adsorption/desorption cycles were performed for As(V) at pH 4 without significant decrease in the uptake performance. ZrBPAP capture capacity and kinetics for arsenate were tested for longevity over 1000 cycles with only a marginal loss of performance. |
申请公布号 |
US2014066529(A1) |
申请公布日期 |
2014.03.06 |
申请号 |
US201314073742 |
申请日期 |
2013.11.06 |
申请人 |
THE UNIVERSITY OF MONTANA |
发明人 |
ROSENBERG EDWARD;KAILASAM VARADHARAJAN;NIELSEN DANIEL |
分类号 |
C02F1/42 |
主分类号 |
C02F1/42 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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