发明名称 PROCESS FOR PRODUCING UNSATURATED ALDEHYDE AND/OR UNSATURATED CARBOXYLIC ACID
摘要 PROBLEM TO BE SOLVED: To provide a safe and stable, high-yield process for producing acrolein, acrylic acid, methacrolein and methacrylic acid, which can, when catalytically oxidizing propylene, isobutylene or the like in a gas phase, avoid a phenomenon where an abnormal reaction is caused by considerable increase in temperature of a catalyst loaded in a reaction tube at an inlet side of a raw material than that at an outlet side of the raw material gas.SOLUTION: There is provided a production process, wherein catalyst and catalyst loading specifications are designed so that a specific condition of 0.5≤Cmax-Ccrs is satisfied, wherein Cmax represents a rate of raw material conversion at which a yield of a desired product becomes maximum; and Ccrs represents a rate of raw material conversion at which, when a maximum temperature of a catalyst layer Zin is denoted by Tin and the maximum temperature of a catalyst layer Zout is denoted by Tout, a magnitude relation of Tin and Tout reverses.
申请公布号 JP2014019675(A) 申请公布日期 2014.02.03
申请号 JP20120161353 申请日期 2012.07.20
申请人 NIPPON KAYAKU CO LTD 发明人 KURAGAMI TATSUHIKO;MATSUMOTO SUSUMU;SUDO ATSUSHI;SHIRAISHI KAZUO;HASHIBA TADASHI
分类号 C07C27/00;C07B61/00;C07C45/35;C07C47/22;C07C51/215;C07C57/055 主分类号 C07C27/00
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