发明名称 Process for isomerization of alkylcyclohexylbenzene
摘要 <p>A process for effectively producing a 4-(4-alkylcyclohexyl)benzaldehyde, 4-(cyclohexyl)benzaldehyde, a 4-(trans-4-alkylcyclohexyl)benzaldehyde and a (trans-4-alkylcyclohexyl)benzene useful for electronic material applications such as liquid crystals and for pharmaceutical and agrochemical applications, etc., are disclosed. The present invention provides (1) a process for producing a 4-(4-alkylcyclohexyl)benzaldehyde or 4-(cyclohexyl)benzaldehyde by formylating a (4-alkylcyclohexyl)benzene or cyclohexylbenzene with carbon monoxide, (2) a process for producing a 4-(trans-4-alkylcyclohexyl)benzaldehyde by formylating a (4-alkylcyclohexyl)benzene having a cis/trans molar ratio of 0.3 or less with carbon monoxide, and (3) a process for producing a (trans-4-alkylcyclohexyl)benzene by isomerizing a mixture of the cis and trans isomers of a (4-alkylcyclohexyl)benzene, all of the processes being performed in the presence of HF and BF 3 .</p>
申请公布号 EP2457888(B1) 申请公布日期 2013.12.04
申请号 EP20120154236 申请日期 2007.05.08
申请人 MITSUBISHI GAS CHEMICAL COMPANY, INC. 发明人 KITAMURA, MITSUHARU;NISHIUCHI, JUNYA;FUSHIMI, NORIO
分类号 C07C5/22;C07C13/28 主分类号 C07C5/22
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