发明名称 |
METHODS OF MAKING 2,3,3,3-TETRAFLUORO-2-PROPENE |
摘要 |
<p>Disclosed is a process for the manufacture of 1234yf from 1,1,2,3-tetrachloropropene, abbreviated herein as“TCP,”in three integrated steps: (a) the R-1 hydrofluorination of TCP to form 1233xf in the vapor phase; (b) the R-2 hydrofluorination of 1233xf to form 244bb in either the liquid phase or in the liquid phase followed by the vapor phase; and (c) the R-3 dehydrochlorination of the 244bb in either the liquid or the vapor phase to produce 1234yf; wherein the vapor phase hydrofluorination of TCP in step (a) is carried out at a lower pressure than the liquid phase hydrofluorination of 123xf; and wherein the HCl generated during these steps is scrubbed with water to form an acid solution and the organic components are scrubbed with a caustic solution and then dried before further processing.</p> |
申请公布号 |
EP2665696(A1) |
申请公布日期 |
2013.11.27 |
申请号 |
EP20120737145 |
申请日期 |
2012.01.13 |
申请人 |
HONEYWELL INTERNATIONAL INC. |
发明人 |
COTTRELL, STEPHEN A.;CHIU, YUON;TUNG, HSUEH SUNG;UHRICH, KEVIN D.;SCHEIDLE, PETER;KOPKALLI, HALUK |
分类号 |
C07C17/25;B01J23/18;C07C17/087;C07C17/21;C07C17/38;C07C21/18 |
主分类号 |
C07C17/25 |
代理机构 |
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代理人 |
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主权项 |
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地址 |
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