Methods for Operating a Polymerization Reactor

摘要

Methods for shutting down and restarting polymerization in a gas phase polymerization reactor are provided. The method can include introducing a polymerization neutralizer to the reactor in an amount sufficient to stop polymerization therein. The method can also include stopping recovery of a polymer product from the reactor and stopping introduction of a catalyst feed and a reactor feed to the reactor. The method can also include adjusting a pressure within the reactor from an operating pressure to an idling pressure. The method can also include adjusting a superficial velocity of a cycle fluid through the reactor from an operating superficial velocity to an idling superficial velocity. The method can also include maintaining the reactor in an idled state for a period of time.