发明名称 METHOD OF OBTAINING 3-ARYL-1,5,3-DITHIAZEPANES
摘要 FIELD: chemistry. ^ SUBSTANCE: method of obtaining 3-aryl-1,5,3-dithiazepanes of general formula , where R=H, m-Me, n-MeO, m-NO2, lies in the following: 3-tret-butyl-1,5,3-dithiazepane is subjected to interaction with N-arylamines (aniline, m-methylaniline, n-methoxyaniline, m-nitroaniline) in presence of catalyst Sm(NO3)36H2O in mole ratio 3-tret-butyl-1,5,3-dithiazepane : N-arylamine : Sm(NO3)36H2O=10:(10-12):(0.3-0.7) in chlorophorm and argon atmosphere for 2.5-3.5 h. ^ EFFECT: elaborated is method of obtaining with high selectivity of novel 3-aryl-1,5,3-dithiazepanes, which can be applied as antibacterial, antifungal and antiviral agents, as complexing agents, selective sorbents and extractants of precious metals, special reagents for suppression of vital activity of bacteria in various technical media. ^ 1 cl, 1 tbl, 1 ex
申请公布号 RU2466997(C1) 申请公布日期 2012.11.20
申请号 RU20110121864 申请日期 2011.05.30
申请人 UCHREZHDENIE ROSSIJSKOJ AKADEMII NAUK INSTITUT NEFTEKHIMII I KATALIZA RAN 发明人 DZHEMILEV USEIN MEMETOVICH;MURZAKOVA NATALIJA NAIL'EVNA;PROKOF'EV KIRILL IGOREVICH;IBRAGIMOVA ASKHAT GABDRAKHMANOVICH;KORZHOVA LJUBOV' FEDOROVNA
分类号 C07D285/36 主分类号 C07D285/36
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